C−H···Br-M Interactions at Work: Tetrabromometalates of the Bolaamphiphilic N,N‘-Dodecamethylenedipyridinium Cation

Autor:	Alessandra Crispini, Francesco Neve and
Rok vydání:	2001
Předmět:	chemistry.chemical_classification Chemistry Inorganic chemistry Halide Salt (chemistry) General Chemistry Crystal structure Condensed Matter Physics Metal chemistry.chemical_compound Crystallography Bromide visual_art visual_art.visual_art_medium General Materials Science Pyridinium
Zdroj:	Crystal Growth & Design. 1:387-393
ISSN:	1528-7505 1528-7483
Popis:	The organic−inorganic hybrid salts [Py−C12−Py][MX4] (M = Pd, Cu; X = Cl, Br) were prepared by reaction of the N,N‘-dodecamethylenedipyridinium cation [Py−C12−Py]2+ and the appropriate halide metal salt. The crystal structures of the bromide derivatives [Py−C12−Py][PdBr4] (3) and [Py−C12−Py][CuBr4] (4) were determined by X-ray crystallography. The presence of several C−H···Br−M contacts between organic cations and inorganic anions leads to segregation of the polymethylene chains. These are arranged in columns which are surrounded by bound pyridinium cation headgroups and isolated tetrabromometalates. The role of C−H···Br−M interactions in crystalline species has been investigated through a CSD search and subsequent analysis.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::378327613ebebf84d86854e2e467d569 https://doi.org/10.1021/cg0155346 Zobrazit plný text záznamu