Hydrothermal Synthesis And Characterization Of A Novel Supramolecular Hybrid Based On Keggin And Cu(I) Complex
| Autor: | Mehtap Emirdag-Eanes, Banu Önen |
|---|---|
| Přispěvatelé: | TR58073, TR58612, Emirdag-Eanes, Mehtap, Önen, Banu, Izmir Institute of Technology. Chemistry |
| Rok vydání: | 2013 |
| Předmět: |
Materials science
Hydrogen bond Inorganic chemistry Supramolecular chemistry Infrared spectroscopy Hydrothermal Hydrothermal circulation Inorganic Chemistry Crystallography Materials Chemistry Molecule Hydrothermal synthesis Keggin Physical and Theoretical Chemistry Polyoxoanion Science technology and society Single crystal |
| Popis: | A novel inorganic-organic hybrid molecule, [Cu(4,4'bipyH)(3)(4,4bipy)][HPW12O40](2)center dot 12H(2)O (1), has been hydrothermally synthesized and characterized by IR spectra, TG and single crystal X-ray diffraction analyses. Structural analysis reveals that the novel compound 1 composed of two Kegging polyoxoanion connected with Cu complex fragment forming a big molecule that extends in 3D via hydrogen bonding. (C) 2013 Elsevier B.V. All rights reserved. |
| Databáze: | OpenAIRE |
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