Stevens Rearrangement of Ammonium Salts Containing 3-Methyl-3-ethoxycarbonylbutanon-2-yl Group

Autor:	G. A. Panosyan, A. V. Babakhanyan, V. S. Ovsepyan, S. T. Kocharyan
Rok vydání:	2003
Předmět:	Sodium Organic Chemistry chemistry.chemical_element Ether General Medicine Medicinal chemistry chemistry.chemical_compound chemistry Stevens rearrangement Group (periodic table) Organic chemistry Ammonium Total acid Benzene
Zdroj:	Russian Journal of Organic Chemistry. 39:820-824
ISSN:	1070-4280
DOI:	10.1023/b:rujo.0000003158.77574.20
Popis:	Ammonium salts containing alongside 3-methyl-3-ethoxycarbonylbutanon-2-yl also 2-alkenyl or benzyl groups under the treatment with Na2CO3·10H2O afford products resulting from Stevens rearrangement. In the mentioned salts the ketoester group on treatment with sodium ethylate suspension in ether or benzene suffers partial or total acid cleavage, and then the Stevens 3,2-rearrangement takes place.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::373596dbbadcfea5cf1fc5948aea065f https://doi.org/10.1023/b:rujo.0000003158.77574.20 Zobrazit plný text záznamu Plný text ve formátu PDF