Thermal decomposition of 4-fluorobenzenediazonium perfluoroorganyl(fluoro)borates, [4-FC6H4N2]Y (Y=RFBF3 (RF=C6F5, C6F13, trans-C4F9CFCF, cis-C6F13CFCF, CF3CC) and (C6F13)2BF2)

Autor:	Vadim V. Bardin, Hermann-Josef Frohn
Rok vydání:	2013
Předmět:	Organic Chemistry Inorganic chemistry Thermal decomposition Chemie chemistry.chemical_element Nuclear magnetic resonance spectroscopy Biochemistry Medicinal chemistry Inorganic Chemistry chemistry Product (mathematics) Environmental Chemistry Physical and Theoretical Chemistry Boron
Zdroj:	Journal of Fluorine Chemistry. 156:333-338
ISSN:	0022-1139
DOI:	10.1016/j.jfluchem.2013.08.001
Popis:	Heating of the neat salts [4-FC6H4N2][RFBF3] (RF = C6F5, C6F13, trans-C4F9CF CF, cis-C6F13CF CF, CF3C C) or in solid mixtures with NaF gives the principal product 1,4-C6F2H4 besides RFBF2 or Na[RFBF3], respectively. Thermolysis of [4-FC6H4N2][(C6F13)2BF2] in NaF results in 1,4-C6F2H4, Na[BF4], Na[(C6F13)2BF2], and a new type of product, the isomer Na[C6F13CF(BF3)C5F11].
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::37334c1bfb50f183036b4fb10efdd6d8 https://doi.org/10.1016/j.jfluchem.2013.08.001 Zobrazit plný text záznamu Full Text from ScienceDirect