| Autor: |
Amine Garci, Arthur H. G. David, Laura Le Bras, Marco Ovalle, Seifallah Abid, Ryan M. Young, Wenqi Liu, Chandra S. Azad, Paige J. Brown, Michael R Wasielewski, J. Fraser Stoddart |
| Rok vydání: |
2022 |
| Předmět: |
|
| Zdroj: |
Journal of the American Chemical Society. |
| ISSN: |
1520-5126 |
| Popis: |
Motion-induced change in emission (MICE) is a phenomenon that can be employed to develop various types of probes, including temperature and viscosity sensors. Although MICE, arising from the conformational motion in particular compounds, has been studied extensively, this phenomenon has not been investigated in depth in mechanically interlocked molecules (MIMs) undergoing coconformational changes. Herein, we report the investigation of a thermoresponsive dynamic homo[2]catenane incorporating pyrene units and displaying relative circumrotational motions of its cyclophanes as evidenced by variable-temperature |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
|
