Unusual Behavior of 2- and 4-Vinyl Pyridines in Polymerization Processes Initiated by Tris-π Allyl Chromium
| Autor: | B. L. Erussalimsky, A. V. Yakimansky, L. A. Fedorova |
|---|---|
| Rok vydání: | 1995 |
| Předmět: |
CHROMIUM COMPLEX
Quantum chemical Tris Polymers and Plastics organic chemicals technology industry and agriculture chemistry.chemical_element Solution polymerization macromolecular substances General Chemistry Chromium chemistry.chemical_compound chemistry Polymerization Polymer chemistry Pyridine Materials Chemistry Ceramics and Composites Reactivity (chemistry) |
| Zdroj: | Scopus-Elsevier |
| ISSN: | 1060-1325 |
| DOI: | 10.1080/10601329508020326 |
| Popis: | In contrast to the data related to the BuLi-vinyl pyridine systems, 4-vinyl pyridine is distinguished by much greater activity as compared with 2-vinyl pyridine in the polymerization induced by tris-π-allyl chronium. The experimental results illustrating this difference are considered using the quantum chemical approach. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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