Martian Atmospheric Chemistry of HCl: Implications for the Lifetime of Atmospheric Methane

Autor: Benjamin M. Taysum, Paul I. Palmer, Mikhail Luginin, Nikolay Ignatiev, Alexander Trokhimovskiy, Alexey Shakun, Alexey Grigoriev, Franck Montmessin, Oleg Korablev, Kevin Olsen
Jazyk: angličtina
Rok vydání: 2023
Předmět:
Popis: We develop a 1-D atmospheric photochemistry model for Mars to interpret hydrogen chloride (HCl) profile measurements collected by the ACS MIR spectrometer aboard the ExoMars Trace Gas Orbiter (TGO) in Mars Year (MY) 34. We include a gas-phase chlorine chemistry scheme and study 1) surface chemistry, 2) hydrolysis, 3) photolysis, and 4) hydration and photolysis of dust grains as possible sources of gas-phase chlorine chemistry. Heterogeneous uptake of chlorine species onto water ice and minerals in Martian dust are loss processes common to all mechanisms. We drive the 1-D model using TGO profile measurements of aerosols and water vapour. We find that mechanism four can reproduce observed HCl profile tendencies during MY34. It reproduces the HCl cut-off at high southern latitudes (
Databáze: OpenAIRE