The use of model cellulose gel beads to clarify flame-retardant characteristics of layer-by-layer nanocoatings
| Autor: | Oruç Köklükaya, Rose-Marie Pernilla Karlsson, Federico Carosio, Lars Wågberg |
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| Rok vydání: | 2020 |
| Předmět: |
Thermogravimetric analysis
Materials science Polymers and Plastics Organic Chemistry Layer by layer 02 engineering and technology engineering.material 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Chitosan chemistry.chemical_compound Sodium hexametaphosphate Coating chemistry Chemical engineering Materials Chemistry engineering Thermal stability Cellulose 0210 nano-technology Intumescent |
| Zdroj: | Carbohydrate polymers. 255 |
| ISSN: | 1879-1344 |
| Popis: | Layer-by-Layer (LbL) assembled nanocoatings are exploited to impart flame-retardant properties to cellulosic substrates. A model cellulose material can make it possible to investigate an optimal bilayer (BL) range for the deposition of coating while elucidating the main flame-retardant action thus allowing for an efficient design of optimized LbL formulations. Model cellulose gel beads were prepared by dissolving cellulose-rich fibers followed by precipitation. The beads were LbL-treated with chitosan (CH) and sodium hexametaphosphate (SHMP). The char forming properties were studied using thermal gravimetric analysis. The coating increased the char yield in nitrogen to up to 29 % and showed a distinct pattern of micro intumescent behavior upon heating. An optimal range of 10-20 BL is observed. The well-defined model cellulose gel beads hence introduce a new scientific route both to clarify the fundamental effects of different film components and to optimize the composition of the films. |
| Databáze: | OpenAIRE |
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