Novel Magnetic Nanohybrids: From Iron Oxide to Iron Carbide Nanoparticles Grown on Nanodiamonds
| Autor: | Ondrej Malina, Jiri Tucek, Panagiotis Ziogas, Athanasios B. Bourlinos, Alexios P. Douvalis |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2020 |
| Předmět: |
Materials science
magnetic nanohybrid materials Iron oxide Maghemite Nanoparticle Fe3C oxid železa spinelového typu spinel-type iron oxide engineering.material iron carbides Nanomaterials Carbide lcsh:Chemistry chemistry.chemical_compound Materials Chemistry Nanodiamond Cementite Mössbauer spectroscopy Mössbauerova spektroskopie Electronic Optical and Magnetic Materials chemistry Chemical engineering lcsh:QD1-999 Chemistry (miscellaneous) nanodiamonds nanodiamantů engineering karbidy železa nanoparticles magnetické nanohybridní materiály nanočástice Superparamagnetism |
| Zdroj: | Magnetochemistry Volume 6 Issue 4 Magnetochemistry, Vol 6, Iss 73, p 73 (2020) |
| ISSN: | 2312-7481 |
| DOI: | 10.3390/magnetochemistry6040073 |
| Popis: | The synthesis and characterization of a new line of magnetic hybrid nanostructured materials composed of spinel-type iron oxide to iron carbide nanoparticles grown on nanodiamond nanotemplates is reported in this study. The realization of these nanohybrid structures is achieved through thermal processing under vacuum at different annealing temperatures of a chemical precursor, in which very fine maghemite (&gamma Fe2O3) nanoparticles seeds were developed on the surface of the nanodiamond nanotemplates. It is seen that low annealing temperatures induce the growth of the maghemite nanoparticle seeds to fine dispersed spinel-type non-stoichiometric ~5 nm magnetite (Fe3&minus xO4) nanoparticles, while intermediate annealing temperatures lead to the formation of single phase ~10 nm cementite (Fe3C) iron carbide nanoparticles. Higher annealing temperatures produce a mixture of larger Fe3C and Fe5C2 iron carbides, triggering simultaneously the growth of large-sized carbon nanotubes partially filled with these carbides. The magnetic features of the synthesized hybrid nanomaterials reveal the properties of their bearing magnetic phases, which span from superparamagnetic to soft and hard ferromagnetic and reflect the intrinsic magnetic properties of the containing phases, as well as their size and interconnection, dictated by the morphology and nature of the nanodiamond nanotemplates. These nanohybrids are proposed as potential candidates for important technological applications in nano-biomedicine and catalysis, while their synthetic route could be further tuned for development of new magnetic nanohybrid materials. |
| Databáze: | OpenAIRE |
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