Development of a dispersive liquid-liquid microextraction method for the determination of polychlorinated biphenyls in water
| Autor: | Fatemeh Rezaei, Yaghoub Assadi, Afsoon Pajand Birjandi, Araz Bidari, Mohammad Reza Milani Hosseini |
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| Rok vydání: | 2007 |
| Předmět: |
Detection limit
Environmental Engineering Chromatography Health Toxicology and Mutagenesis Extraction (chemistry) Analytical chemistry Reproducibility of Results Pollution Polychlorinated Biphenyls Sensitivity and Specificity Electron capture detector chemistry.chemical_compound chemistry Chlorobenzene Environmental Chemistry Seawater Sample preparation Gas chromatography Enrichment factor Waste Management and Disposal Water Pollutants Chemical |
| Zdroj: | Journal of hazardous materials. 158(2-3) |
| ISSN: | 0304-3894 |
| Popis: | A very simple and powerful microextraction procedure, the dispersive liquid–liquid microextraction (DLLME), was used for the determination of the content of 10 polychlorinated biphenyls (PCBs) in water samples, using gas chromatography coupled with electron-capture detection (GC–ECD). The appropriate amount of acetone (disperser solvent) and chlorobenzene (extraction solvent) at the microlevel volume was used for this procedure. The conditions for the microextraction performance were investigated and optimized. The optimized method exhibited a good linearity (R 2 > 0.996) over the studied range (0.005–2 gL −1 ), illustrating a satisfactory precision level with R.S.D. values between 4.1% and 11.0%. The values of the detection limit (S/N = 3) were found to be lower than 0.002 gL −1 . Furthermore, a large enrichment factor for the analytes (up to a 540-fold) was achieved in a very short time for only a 5.00-mL water sample. The effectiveness of the method towards real samples was tested by analyzing well, river and seawater samples. The relative recoveries of the well, river and seawater samples, which had been spiked with different levels of PCBs were equal to 92.0–114.0%, 97.0–102.0% and 96.0–103.0%, respectively. The attained results demonstrated that DLLME combined with GC–ECD was a fast and inexpensive technique for the PCBs determination in water samples. © 2008 Elsevier B.V. All rights reserved. |
| Databáze: | OpenAIRE |
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