| Autor: |
J. Thomas James, Philip Mountford, Graham H. Maunder, Peter C. Konidaris, Malcolm L. H. Green, Jennifer C. Green |
| Rok vydání: |
2016 |
| Předmět: |
|
| DOI: |
10.1039/c39920001361 |
| Popis: |
The pseudo-trigonal bis(η-cyclopentadienyl)-molybdenum and -tungsten imido complexes [M(η-C5H4R)(η-C5H4R′)(NBut)](M = Mo or W; R = R′= Me or H, R′= Pri R = H) are reported together with the ring-slipped indenyl analogue [Mo(η-C5H4Pri)(η3-C9H7)(NBut)] and the metal-methylated salts [Mo(η-C5H4Me)2(NBut)Me]X (X = I or BF4); the X-ray structures of [Mo(η-C5H5)2(NBut)] and [Mo(η-C5H4Me)2(NBut)Me]BF4 suggest that the NBut ligand acts as a strong π-donor to the metal centre; photoelectron studies identify an unusually low ionization-energy band largely localized on the ligands. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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