DC conductivity, cationic exchange capacity, and specific surface area related to chemical composition of pore lining chlorites
| Autor: | Claudine Durand, Etienne Brosse, Jean-Charles Giuntini, François Henn, Adrian Cerepi |
|---|---|
| Přispěvatelé: | Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier (ICGM ICMMM), Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Centre National de la Recherche Scientifique (CNRS)-Université de Montpellier (UM)-Université Montpellier 1 (UM1)-Université Montpellier 2 - Sciences et Techniques (UM2)-Institut de Chimie du CNRS (INC), IFP Energies nouvelles (IFPEN) |
| Jazyk: | angličtina |
| Rok vydání: | 2007 |
| Předmět: |
Moisture
Chemistry Mineralogy 02 engineering and technology Activation energy Conductivity 010502 geochemistry & geophysics 021001 nanoscience & nanotechnology 01 natural sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Biomaterials [CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistry chemistry.chemical_compound Colloid and Surface Chemistry Chemical engineering Electrical resistivity and conductivity Specific surface area Cation-exchange capacity 0210 nano-technology Chlorite Chemical composition 0105 earth and related environmental sciences |
| Zdroj: | Journal of Colloid and Interface Science Journal of Colloid and Interface Science, Elsevier, 2007, 311 (2), pp.571-578. ⟨10.1016/j.jcis.2007.02.062⟩ |
| ISSN: | 0021-9797 1095-7103 |
| DOI: | 10.1016/j.jcis.2007.02.062⟩ |
| Popis: | International audience; Low resistivity in argillaceous sandstone reservoirs may be attributed either to the effect of microporosity, or to specific effects due to intrinsic clays' conducting properties or to other conducting minerals. In order to distinguish these effects, cation exchange capacity, specific surface areas, and dc conductivity of various pore lining chlorite-bearing sandstones from different hydrocarbon reservoir measurements are investigated. Cation exchange capacity and specific surface area are measured on whole rocks as well as on size-separated fractions. Both sets of values are low, in agreement with the structural and textural observations. The conductivity of these chlorites, measured in air conditions and after dehydration, is investigated by means of complex impedance spectroscopy on size-separated fractions as a function of temperature and compared to that of reference clays. The results show a large influence of moisture, applied electric field frequency, and temperature on the electrical properties. The magnitude of the dehydrated clays' conductivity is such that its influence on the conductivity of argillaceous sandstone is lower than that related to the presence of water or brine by several orders of magnitude. The dc, conductivity and the related activation energy of the dehydrated samples appear to be related to the chemical composition of the clays. More specifically, a clear correlation occurs with the electrical charges of the clay network, that is to say with the location, i.e., tetrahedral or octahedral sites, of the substituting trivalent elements. |
| Databáze: | OpenAIRE |
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