A Hexakis Terpyridine-Fullerene Ligand in Six-Fold Ruthenium, Iridium, and Iron Complexes: Synthesis and Electrochemical Properties
| Autor: | Sebastian Menning, Weibo Yan, Thierry Muller, Céline Réthoré, Philippe Pierrat, Stefan Bräse, Gerald Brenner-Weiß |
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| Přispěvatelé: | Karlsruhe Institute of Technology (KIT), Chimie, Ingénierie Moléculaire et Matériaux d'Angers (CIMMA), Université d'Angers (UA)-Centre National de la Recherche Scientifique (CNRS), Structure et Réactivité des Systèmes Moléculaires Complexes (SRSMC), Université de Lorraine (UL)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC), Institute of Organic Chemistry [Karlsruhe] |
| Jazyk: | angličtina |
| Rok vydání: | 2016 |
| Předmět: |
chemistry.chemical_classification
Fullerene 010405 organic chemistry [CHIM.ORGA]Chemical Sciences/Organic chemistry Organic Chemistry chemistry.chemical_element General Chemistry [CHIM.CATA]Chemical Sciences/Catalysis 010402 general chemistry Photochemistry 01 natural sciences Catalysis 3. Good health 0104 chemical sciences Ruthenium chemistry.chemical_compound chemistry Polymer chemistry Fullerene ligand Bingel reaction Iridium Terpyridine Cyclic voltammetry Crown ether ComputingMilieux_MISCELLANEOUS |
| Zdroj: | Chemistry-A European Journal Chemistry-A European Journal, Wiley-VCH Verlag, 2016, 22 (33), pp.11522-11526. ⟨10.1002/chem.201600796⟩ |
| ISSN: | 0947-6539 1521-3765 |
| DOI: | 10.1002/chem.201600796⟩ |
| Popis: | An unprecedented straightforward route to six-fold terpyridine ligands around C60 , the latter being regioselectively functionalized in pseudo-octahedral positions using a six-fold Bingel reaction, is reported. Ruthenium, iridium, and iron complexes have been synthesized, and unambiguously characterized by NMR, MS, and cyclic voltammetry. |
| Databáze: | OpenAIRE |
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