Medium- and large-ring heterocyclic systems by intramolecular nitrile imine cycloadditions

Autor:	Luisa Garanti, Gianluigi Broggini, Luca Bruché, Gaetano Zecchi
Rok vydání:	1994
Předmět:	chemistry.chemical_compound Intramolecular reaction Nitrile Chemistry Nitrilimine Stereochemistry Intramolecular force Imine Ring (chemistry) Medicinal chemistry Cycloaddition Silver carbonate
Zdroj:	Scopus-Elsevier
ISSN:	1364-5463 0300-922X
DOI:	10.1039/p19940000433
Popis:	A series of hydrazonyl chlorides bearing an alkenyl chain have been synthesised and treated with silver carbonate. The propensity of the so-formed nitrite Imine intermediates to undergo intramolecular cycloaddition is markedly dependent on the length and the flexibility of the chain. The latter also affected the regio- and the stereo-chemistry of the Intramolecular process. In certain circumstances, tandem intermolecular–Intramolecular cycloadditions took place, to produce largering heterophanes.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::35a335639bc7c6841ea23e2437a1efde https://doi.org/10.1039/p19940000433 Zobrazit plný text záznamu