Gold-Catalyzed Cycloisomerization of 1,6-Cyclohexenylalkyne: An Efficient Entry to Bicyclo[3.2.1]oct-2-ene and Bicyclo[3.3.1]nonadiene

Autor: Jean-Marie Fourquez, Fabien Fontaine-Vive, Vincent Davenel, Christian Nisole, Véronique Michelet, Anne-Marie Chollet
Rok vydání: 2020
Předmět:
Zdroj: The Journal of organic chemistry. 85(19)
ISSN: 1520-6904
Popis: An efficient and mild synthetic route for the preparation of functionalized bicyclo[3.2.1]oct-2-ene and bicyclo[3.3.1]nonadiene via gold-mediated cycloisomerization of 1,6-enynes has been developed. This atom-economical catalytic process was optimized and relied on the efficiency of IPrAuNTf
Databáze: OpenAIRE