Role of Phosphine Sterics in Strained Aminophosphine Chelate Formation
| Autor: | Jennifer A. Love, D. Dawson Beattie, Eric G. Bowes |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
Steric effects
010405 organic chemistry 010402 general chemistry 01 natural sciences 3. Good health 0104 chemical sciences Ring strain Inorganic Chemistry Metal chemistry.chemical_compound chemistry visual_art Polymer chemistry visual_art.visual_art_medium Chelation Physical and Theoretical Chemistry Phosphine |
| Zdroj: | Inorganic Chemistry. 58:2925-2929 |
| ISSN: | 1520-510X 0020-1669 |
| DOI: | 10.1021/acs.inorgchem.8b03514 |
| Popis: | The preparation of four-membered aminophosphine (PN) chelates from common metal precursors has largely evaded realization because of the ring strain associated with these species. We report a straightforward approach to the synthesis of such PN metallacycles using simple α-PN ligands analogous to the popular class of small-bite-angle diphosphinomethane ligands. It is demonstrated that bulky phosphine substituents are important to the formation of these chelates. |
| Databáze: | OpenAIRE |
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