Retention-time database of 126 polybrominated diphenyl ether congeners and two Bromkal technical mixtures on seven capillary gas chromatographic columns
| Autor: | Adrian Covaci, Anke Gelbin, Jacob de Boer, Udo A. Th. Brinkman, Peter Korytár |
|---|---|
| Rok vydání: | 2005 |
| Předmět: |
Chromatography
Gas Polybrominated Biphenyls carp cyprinus-carpio computer.software_genre Biochemistry brominated flame retardants Analytical Chemistry chemistry.chemical_compound Polybrominated diphenyl ethers blood Halogenated Diphenyl Ethers samples Chromatography Database Elution Phenyl Ethers Organic Chemistry Diphenyl ether General Medicine RIVO Milieu en Voedselveiligheid Hydrocarbons Brominated pbdes Electron capture detector Congener chemistry debromination identification Gas chromatography computer Algorithms Ethers Fire retardant |
| Zdroj: | Journal of chromatography: A Journal of Chromatography. A, Including electrophoresis and other separation methods, 1065(2), 239-249 Journal of Chromatography. A, Including electrophoresis and other separation methods 1065 (2005) 2 |
| ISSN: | 0021-9673 |
| DOI: | 10.1016/j.chroma.2004.12.059 |
| Popis: | The elution order of 126 polybrominated diphenyl ethers (PBDE) was determined for seven different gas chromatographic (GC) stationary phases. The resulting database facilitates selection of the most suitable GC columns for developing a quantitative, congener-specific BDE analysis and the testing of retention prediction algorithms based on structure relationships of GC phases and congener substitution patterns. In addition, co-elutions of the principal BDE congeners with other BDEs and/or with other brominated flame retardants were investigated and, as an application, the composition of two Bromkal mixtures (70-5DE and 79-8DE) was studied. (C) 2004 Elsevier B.V. All rights reserved. |
| Databáze: | OpenAIRE |
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