Vinylcyclopropanation of Olefins via 3-Methoxy-1-propenylrhodium(I)

Autor:	Tatsuro Harumashi, Taisuke Sasaki, Masahiro Murakami, Tomoya Miura
Rok vydání:	2006
Předmět:	chemistry.chemical_classification Allylic rearrangement Stereochemistry Leaving group General Medicine General Chemistry Medicinal chemistry Biochemistry Catalysis chemistry.chemical_compound Colloid and Surface Chemistry chemistry Bridged compounds Carbene
Zdroj:	Journal of the American Chemical Society. 128:2516-2517
ISSN:	1520-5126 0002-7863
DOI:	10.1021/ja0575326
Popis:	New cyclization reactions forming vinylcyclopropanes were developed wherein an alkenylrhodium(I) possessing a methoxy group at the allylic position as a potential leaving group acts as an allylic carbene equivalent. By this protocol, a vinylcyclopropane was installed in a complex cyclic structure in a single operation via successive multiple carbon-carbon bond formations.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3543f43650a5fc0db84e131bf9eafc27 https://doi.org/10.1021/ja0575326 Zobrazit plný text záznamu