Self-assembly of [Sn(OPMe3)3(CF3SO3)2]6 metallocyclic Sn(ii ) hexamer stacks with CF3-lined channel interiors
| Autor: | Kelsey R. Cairns, Rhys P. King, William Levason, Gillian Reid |
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| Rok vydání: | 2022 |
| Předmět: | |
| Zdroj: | CrystEngComm. 24:6137-6140 |
| ISSN: | 1466-8033 |
| DOI: | 10.1039/d2ce01029a |
| Popis: | [Sn(OPMe3)3(CF3SO3)2]6 (1) self-assembles to form a highly unusual hexagonal metallocyclic array with bridging CF3SO3− groups. The discrete hexamers stack along the c-axis to form hydrophobic CF3-lined channels with an F⋯F distance across the channel diameter of 0.8 nm. This Sn(ii) complex is different from its Pb(ii) analogue, which instead forms a discrete, doubly CF3SO3-bridged dimer of formula, [{Pb(OPMe3)3(CF3SO3)}2(μ-CF3SO3)2] (3). |
| Databáze: | OpenAIRE |
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