Green synthesis of imine-based covalent organic frameworks in water
| Autor: | Martín-Illán J.Á., Rodríguez-San-Miguel D., Franco C., Imaz I., Maspoch D., Puigmartí-Luis J., Zamora F. |
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| Přispěvatelé: | European Commission, European Research Council, Swiss National Science Foundation, Generalitat de Catalunya, Ministerio de Ciencia, Innovación y Universidades (España), Agencia Estatal de Investigación (España), Ministerio de Economía y Competitividad (España) |
| Rok vydání: | 2020 |
| Předmět: |
One pot
Aqueous solution Aqueous synthesis Chemistry Imine Metals and Alloys 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Combinatorial chemistry Catalysis 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound High yield Microwave conditions Covalent bond Materials Chemistry Ceramics and Composites Synthetic protocols 0210 nano-technology Covalent organic frameworks |
| Zdroj: | Dipòsit Digital de Documents de la UAB Universitat Autònoma de Barcelona Digital.CSIC. Repositorio Institucional del CSIC instname Repositorio Institucional del Instituto Madrileño de Estudios Avanzados en Nanociencia Chemical Communications |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/d0cc02033h |
| Popis: | Dynamic covalent bonds have been advantageously used to direct the synthesis of crystalline porous covalent organic frameworks (COFs). Unlike the standard synthetic protocols that involve harsh conditions, this work provides a high-yield “one-pot” green synthesis of imine-based COFs in water. Additionally, this aqueous synthesis can be performed under microwave conditions, considerably reducing the reaction time. This work was supported by the EU (ERC-2015-STG microCrysFact 677020 and ERC-Co 615954), Swiss National Science Foundation (project no. 200021_160174 and 200021_181988), ETH Zürich, Catalan AGAUR (project 2017 SGR 238), and MICINN (“María de Maeztu” Programme for Units of Excellence in R&D CEX2018-000805-M, MAT2016-77608-C3-1P and RTI2018-095622-B-I00). It was also funded by the CERCA Program/Generalitat de Catalunya. ICN2 is supported by Severo Ochoa program from MINECO (SEV-2017-0706). |
| Databáze: | OpenAIRE |
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