The Pauson-Khand Mechanism Revisited: Origin of CO in the Final Product
| Autor: | Antony Memboeuf, Anne Milet, Andrew E. Greene, Jérôme Blu, Jean-Claude Tabet, Denis Lesage, Yves Gimbert |
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| Přispěvatelé: | Laboratoire de Synthèse Organique et Organométallique (UMR CNRS 7201), Université Pierre et Marie Curie - Paris 6 (UPMC), Département de Chimie Moléculaire (DCM), Université Joseph Fourier - Grenoble 1 (UJF)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Chimie, Electrochimie Moléculaires et Chimie Analytique (CEMCA), Institut Brestois Santé Agro Matière (IBSAM), Université de Brest (UBO)-Université de Brest (UBO)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC), Financial support from the CNRS and the Université Joseph Fourier, and calculation resources provided by CIMENT/CECIC are gratefully acknowledged, Institut Parisien de Chimie Moléculaire (IPCM), Université Pierre et Marie Curie - Paris 6 (UPMC)-Centre National de la Recherche Scientifique (CNRS), Université de Brest (UBO)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Institut Brestois Santé Agro Matière (IBSAM), Université de Brest (UBO) |
| Jazyk: | angličtina |
| Rok vydání: | 2014 |
| Předmět: |
Cyclopentenone
Reaction mechanism gas-phase reactions Final product Analytical chemistry chemistry.chemical_element General Medicine General Chemistry Mass spectrometry Kinetic energy cobalt Catalysis chemistry.chemical_compound reaction mechanisms chemistry Computational chemistry [CHIM.ANAL]Chemical Sciences/Analytical chemistry Product (mathematics) density functional calculations [CHIM]Chemical Sciences Cobalt Carbon monoxide mass spectrometry |
| Zdroj: | Angewandte Chemie International Edition Angewandte Chemie International Edition, Wiley-VCH Verlag, 2014, 53 (7), pp.1939-1942. ⟨10.1002/anie.201307745⟩ Angewandte Chemie International Edition, 2014, 53 (7), pp.1939-1942. ⟨10.1002/anie.201307745⟩ |
| ISSN: | 1433-7851 1521-3773 |
| DOI: | 10.1002/anie.201307745⟩ |
| Popis: | International audience; The mechanism of the Pauson–Khand reaction has been studied by mass spectrometry and it has been found, through ion-molecule reaction with 13CO, that the carbon monoxide incorporated into the product cyclopentenone is one that has been retained within the complex. Theoretical and kinetic calculations support this finding, which provides a complementary explanation for the effect of Pauson–Khand promoters. |
| Databáze: | OpenAIRE |
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