Crystallographically aligned carbon nanotubes grown on few-layer graphene films
| Autor: | D. Patrick Hunley, Stephen L. Johnson, Joseph K. Stieha, Abhishek Sundararajan, Aaron T. Meacham, Ilia N. Ivanov, Douglas R. Strachan |
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| Rok vydání: | 2011 |
| Předmět: |
Materials science
Graphene Carbon nanofiber General Engineering Selective chemistry of single-walled nanotubes General Physics and Astronomy Nanotechnology Mechanical properties of carbon nanotubes Carbon nanotube law.invention Optical properties of carbon nanotubes Potential applications of carbon nanotubes Chemical engineering law General Materials Science Graphene nanoribbons |
| Zdroj: | ACS nano. 5(8) |
| ISSN: | 1936-086X |
| Popis: | Carbon nanotubes are grown on few-layer graphene films using chemical vapor deposition without a carbon feedstock gas. We find that the nanotubes show a striking alignment to specific crystal orientations of the few-layer graphene films. The nanotubes are oriented predominantly at 60 degree intervals and are offset 30 degrees from crystallographically oriented etch tracks, indicating alignment to the armchair axes of the few-layer graphene films. Nanotubes grown on various thicknesses of few-layer graphene under identical process conditions show that the thinnest films, in the sub-6 atomic layer regime, demonstrate significantly improved crystallographic alignment. Intricate crystallographic patterns are also observed having sharp kinks with bending radii less than the ∼10 nm lateral resolution of the electron and atomic force microscopy used to image them. Some of these kinks occur independently without interactions between nanotubes while others result when two nanotubes intersect. These intersections can trap nanotubes between two parallel nanotubes resulting in crystallographic back and forth zigzag geometries. These interactions suggest a tip-growth mechanism such that the catalyst particles remain within several nanometers of the few-layer graphene surface as they move leaving a nanotube in their wake. |
| Databáze: | OpenAIRE |
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