A heterogeneous, selective oxidation catalyst based on Mn triazacyclononane grafted under reaction conditions
| Autor: | Nicholas J. Schoenfeldt, Andrew W. Korinda, Justin M. Notestein |
|---|---|
| Rok vydání: | 2010 |
| Předmět: |
In situ
Reaction conditions Inorganic chemistry Metals and Alloys chemistry.chemical_element General Chemistry Manganese Grafting Combinatorial chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Catalytic oxidation chemistry Homogeneous Materials Chemistry Ceramics and Composites |
| Zdroj: | Chemical communications (Cambridge, England). 46(10) |
| ISSN: | 1364-548X |
| Popis: | A unique method has been developed to synthesize an active heterogeneous oxidation catalyst by the in situ grafting of a 1,4,7-trimethyl-1,4,7-triazacyclononane manganese complex on carboxylic acid-functionalized supports serving dual roles as surface tether and necessary co-catalyst, massively increasing total turnovers as compared to the homogeneous analog. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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