Ge(ii) cation catalyzed hydroboration of aldehydes and ketones

Autor: Pritam Mahawar, Selvarajan Nagendran, Rahul Kumar Siwatch, Manish Sharma, Soumen Sinhababu, Dharmendra Singh
Rok vydání: 2019
Předmět:
Zdroj: Dalton Transactions. 48:4094-4100
ISSN: 1477-9234
1477-9226
Popis: Well-defined germylene cations [(i-Bu)2ATI]GeOTf (4) and [(i-Bu)2ATIGe][GaCl4] (5) are isolated, and the catalytic utility of compound 4 for the hydroboration of a variety of aldehydes and ketones is reported (ATI = aminotroponiminate).
Databáze: OpenAIRE