Nonracemic 2-Diazo-1-oxiranyl-ethanone, a Versatile Chiral Epoxide Educt in Diazocarbonyl Reactions

Autor:	Hugues Miel, McKervey Ma, Michelle Groarke, Mark Nieuwenhuyzen
Rok vydání:	2000
Předmět:	chemistry.chemical_compound Quinoxaline chemistry visual_art Yield (chemistry) Organic Chemistry visual_art.visual_art_medium Epoxide Organic chemistry Diazo Epoxy Physical and Theoretical Chemistry Biochemistry
Zdroj:	Organic Letters. 2:2393-2395
ISSN:	1523-7052 1523-7060
DOI:	10.1021/ol000034b
Popis:	(S)-(-)-2-Diazo-1-oxiranyl-ethanone, prepared in two steps from (R)-(+)-glycidol, has been employed as an intermediate in several characteristic diazocarbonyl reactions to yield novel, nonracemic products including an epoxy quinoxaline and epoxy thiazoles and oxazoles.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3360f0284a9d676ffbad1a28d22ca876 https://doi.org/10.1021/ol000034b Zobrazit plný text záznamu