Macroscopic forces in inhomogeneous polyelectrolyte solutions

Autor:	Yury A. Budkov, Nikolai N. Kalikin
Rok vydání:	2023
Předmět:	Soft Condensed Matter (cond-mat.soft) FOS: Physical sciences Condensed Matter - Soft Condensed Matter
Zdroj:	Physical Review E. 107
ISSN:	2470-0053 2470-0045
DOI:	10.1103/physreve.107.024503
Popis:	In this paper, we present a self-consistent field theory of macroscopic forces in spatially inhomogeneous flexible chain polyelectrolyte solutions. We derive an analytical expression for a stress tensor which consists of three terms: isotropic hydrostatic stress, electrostatic (Maxwell) stress, and stress rising from conformational entropy of polymer chains -- conformational stress. We apply our theory to the description of polyelectrolyte solutions confined in a conductive slit nanopore and observe anomalous behavior of disjoining pressure and electric differential capacitance. Submitted to Physical Review E
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::335a21f918b1edf243b91c272eab6f89 https://doi.org/10.1103/physreve.107.024503 Zobrazit plný text záznamu