Infrared Hole Burning and Conformational Change in a Borane−Ammonia Complex

Autor:	Herbert L. Strauss, Christopher A. Endicott, Dirk Trauner, Chambers C. Hughes
Rok vydání:	2005
Předmět:	Models Molecular Conformational change Hydrogen Infrared Rays Infrared Kinetics Molecular Conformation chemistry.chemical_element Borane Crystallography X-Ray Photochemistry Spectral line Ammonia chemistry.chemical_compound chemistry Atom Physical and Theoretical Chemistry Boranes
Zdroj:	The Journal of Physical Chemistry A. 109:7714-7717
ISSN:	1520-5215 1089-5639
DOI:	10.1021/jp051969i
Popis:	The N-D stretching region in the infrared spectrum of the ammonia complex of tris-(2-methoxymethyl-phenol)-borane containing one D atom has been examined. The N-D bands have been hole burned, and the resulting spectra reveal the reorientation kinetics of the ammonia. The ammonia is hydrogen bonded with the bond distances and reorientation barrier typical of other compounds. The N-D stretching frequencies are higher than those of comparison compounds.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::33055fb86b9f69ea9b4f8d7bdf4f1839 https://doi.org/10.1021/jp051969i Zobrazit plný text záznamu