Formadide as a superior nitrogen nucleophile in palladium(II)mediated synthesis of imidazolidines

Autor:	G. Rodriguez Longarela, R. A. T. M. Van Benthem, Henk Hiemstra, W. N. Speckamp
Přispěvatelé:	HIMS former research (FNWI)
Rok vydání:	1994
Předmět:	Formamide Allylic rearrangement Organic Chemistry Formaldehyde chemistry.chemical_element Biochemistry Catalysis chemistry.chemical_compound chemistry Nucleophile Drug Discovery Organic chemistry Formamides Imidazolidines Palladium
Zdroj:	Tetrahedron Letters, 35. Elsevier
ISSN:	0040-4039
Popis:	Formamides emerge as superior nitrogen nucleophiles in palladium(II) catalyzed oxidative 5-exo cyclizations of formaldehyde aminals derived from N-Boc protected allylic amines. The product imidazolidines are readily transformed into protected vicinal diamines.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::32f1a209cb2526fbcbb18722d7b7649c https://hdl.handle.net/11245/1.105645 Zobrazit plný text záznamu