Mesoporous Silica for Triphase Nucleophilic Substitution Reactions

Autor: Liang Qiao, Jiangfeng Huang, Shouai Feng, Chang Ji, Yixin Li, Ji Ji, Baohong Liu, Hong Liu
Rok vydání: 2018
Předmět:
Zdroj: CHIMIA, Vol 72, Iss 7-8 (2018)
ISSN: 0009-4293
Popis: Mesoporous silica SBA-15 is shown to be a very efficient alternative to phase transfer catalyst salts for two-phase nucleophilic substitutions. The two-phase reaction can efficiently take place in the absence of PTCs. The high catalytic activity and reaction rates can be attributed to the amphiphilic and negatively charged surface of SBA-15 as well as the rapid ingress of the reactants and egress of the products.
Databáze: OpenAIRE