Assisted π-stacking: a strong synergy between weak interactions
| Autor: | Debangshu Chaudhuri, Narottam Mukhopadhyay, Sumit Naskar, Soumik Sao, Mousumi Das |
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| Rok vydání: | 2018 |
| Předmět: |
Materials science
010405 organic chemistry Metals and Alloys Stacking General Chemistry 010402 general chemistry 01 natural sciences Catalysis 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Chemical physics Materials Chemistry Ceramics and Composites Thermal stability Natural bond orbital |
| Zdroj: | Chemical communications (Cambridge, England). 54(86) |
| ISSN: | 1364-548X |
| Popis: | Synergy between a pair of weak non-covalent interactions can predispose a molecular self-assembly towards a specific pathway. We report assisted π-stacking, a synergy between aromatic π-stacking and n →π* interactions that exhibits an unprecedented strength and thermal stability. Natural bond orbital analysis reveals the non-additive nature of the interaction. |
| Databáze: | OpenAIRE |
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