Energetic Chromophores: Low-Energy Laser Initiation in Explosive Fe(II) Tetrazine Complexes
| Autor: | Sergei Tretiak, Susan K. Hanson, Kathryn E. Brown, Jacqueline M. Veauthier, David E. Chavez, Josiah A. Bjorgaard, Thomas W. Myers, R. Jason Scharff |
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| Rok vydání: | 2016 |
| Předmět: |
Explosive material
010405 organic chemistry Ligand General Chemistry Chromophore 010402 general chemistry Photochemistry Laser 01 natural sciences Biochemistry Sensitivity (explosives) Catalysis 0104 chemical sciences law.invention Perchlorate chemistry.chemical_compound Tetrazine Colloid and Surface Chemistry chemistry law Density functional theory |
| Zdroj: | Journal of the American Chemical Society. 138:4685-4692 |
| ISSN: | 1520-5126 0002-7863 |
| Popis: | The synthesis and characterization of air stable Fe(II) coordination complexes with tetrazine and triazolo-tetrazine ligands and perchlorate counteranions have been achieved. Time-dependent density functional theory (TD-DFT) was used to model the structural, electrochemical, and optical properties of these materials. These compounds are secondary explosives that can be initiated with Nd:YAG laser light at lower energy thresholds than those of PETN. Furthermore, these Fe(II) tetrazine complexes have significantly lower sensitivity than PETN toward mechanical stimuli such as impact and friction. The lower threshold for laser initiation was achieved by altering the electronic properties of the ligand scaffold to tune the metal ligand charge transfer (MLCT) bands of these materials from the visible into the near-infrared region of the electromagnetic spectrum. Unprecedented decrease in both the laser initiation threshold and the mechanical sensitivity makes these materials the first explosives that are both safer to handle and easier to initiate than PETN with NIR lasers. |
| Databáze: | OpenAIRE |
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