Molecular hybrids combining magnetic complexes and organic π-donors
| Autor: | F. Bérézovsky, P. Molinie, J. Sala Pala, A. Riou, Smail Triki |
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| Přispěvatelé: | Chimie, Electrochimie Moléculaires et Chimie Analytique (CEMCA), Institut Brestois Santé Agro Matière (IBSAM), Université de Brest (UBO)-Université de Brest (UBO)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC) |
| Jazyk: | angličtina |
| Rok vydání: | 1999 |
| Předmět: |
Magnetic measurements
Chemistry Stereochemistry Mechanical Engineering Metals and Alloys chemistry.chemical_element 02 engineering and technology Crystal structure 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences Oxalate 0104 chemical sciences Electronic Optical and Magnetic Materials Ion Crystallography Chromium chemistry.chemical_compound Mechanics of Materials Materials Chemistry [CHIM]Chemical Sciences 0210 nano-technology Molecular materials |
| Zdroj: | Synthetic Metals Synthetic Metals, Elsevier, 1999, 103, pp.1974--1975. ⟨10.1016/S0379-6779(98)00902-3⟩ |
| ISSN: | 0379-6779 |
| DOI: | 10.1016/S0379-6779(98)00902-3⟩ |
| Popis: | International audience; Combination of the magnetic dinuclear chromium(III) anion [Cr2(C2O4)(NCS)8]4 with the organic ET π-donor (ET = BEDT-TTF = bis(ethylenedithio)tetrathiafulvalene) yields two novel molecular hybrids (ET)n[Cr2(C2O4)(NCS)8] (1:n = 5; 2:n = 8). The particular arrangement of the organic units in the former leads to an unprecedented two-dimensional organic sublattice nearly similar to that observed in κ-phase structures. The packing of the ET units in 2 is near that observed in β-phase. |
| Databáze: | OpenAIRE |
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