Inorganic/Organic Semiconductor Heterostructures: Optical Properties of Quaterthiophene Intercalated in Cadmium Phosphorus Trisulfide
| Autor: | Peter Spearman, Massimiliano Labate, Luciano Miozzo, Leonardo Silvestri, Hugh O'Malley, Antonio Papagni, Peter J. S. Foot, Silvia Tavazzi |
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| Přispěvatelé: | Labate, M, Foot, P, O'Malley, H, Miozzo, L, Papagni, A, Silvestri, L, Spearman, P, Tavazzi, S |
| Rok vydání: | 2008 |
| Předmět: |
Cadmium
Materials science Photoluminescence Inorganic/Organic Semiconductor Heterostructures Quaterthiophene Intercalates Cadmium Phosphorus Trisulfide transmittance reflectance and luminescence optical spectra Phosphorus Intercalation (chemistry) Inorganic chemistry Analytical chemistry chemistry.chemical_element Surfaces Coatings and Films Electronic Optical and Magnetic Materials General Energy chemistry Transmittance Molecule Lamellar structure Physical and Theoretical Chemistry Refractive index |
| Zdroj: | The Journal of Physical Chemistry C. 112:20149-20153 |
| ISSN: | 1932-7455 1932-7447 |
| DOI: | 10.1021/jp806274w |
| Popis: | The transmittance, reflectance, and photoluminescence optical spectra of lamellar cadmium phosphorus trisulfide ?(CdPS 3 ) crystals are reported, as measured before and after intercalation with quaterthiophene (4T) molecules. The optical properties of pristine CdPS 3 and 4T intercalates have been characterized in the 2-6 eV spectral region by the full complex refractive index. This latter has been deduced from transmittance and reflectance measurements and by Kramers-Kronig relations. The comparison of optical properties of CdPS 3 and its 4T intercalate provide information on the arrangement of the molecules inside the inorganic layers and on the interactions between the organic molecules and between the organic and inorganic components. |
| Databáze: | OpenAIRE |
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