Chiral Analysis Using Broadband Rotational Spectroscopy
| Autor: | Chris Medcraft, Anna Krin, David Schmitz, Sérgio R. Domingos, Cristobal Perez, David Patterson, V. Alvin Shubert, Melanie Schnell |
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| Rok vydání: | 2016 |
| Předmět: |
010405 organic chemistry
Chemistry Absolute configuration Analytical chemistry High resolution 010402 general chemistry 01 natural sciences Molecular physics 0104 chemical sciences Broadband Molecule General Materials Science Rotational spectroscopy Physical and Theoretical Chemistry Enantiomer Enantiomeric excess |
| Zdroj: | The Journal of Physical Chemistry Letters |
| ISSN: | 1948-7185 |
| DOI: | 10.1021/acs.jpclett.5b02443 |
| Popis: | Broadband microwave spectroscopy is a proven tool to precisely determine molecular properties of gas-phase molecules. Recent developments make it applicable to investigate chiral molecules. Enantiomers can be differentiated, and the enantiomeric excess and, indirectly, the absolute configuration can be determined in a molecule-selective manner. The resonant character and high resolution of rotational spectroscopy provide a unique mixture compatibility. Future directions, such as extending the technique to chemical analysis, are discussed. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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