Study of the reactions of OH with HCl, HBr, and HI between 298 K and 460 K

Autor:	Igor Larin, Vladimir L. Orkin, Victor G. Khamaganov
Rok vydání:	2022
Předmět:	Inorganic Chemistry chemistry.chemical_compound Reaction rate constant Chemistry Organic Chemistry Hydroxyl radical Physical and Theoretical Chemistry Biochemistry Medicinal chemistry Article
Zdroj:	Int J Chem Kinet
ISSN:	0538-8066
Popis:	The reactions between OH radicals and hydrogen halides (HCl, HBr, HI) have been studied between 298 and 460 K by using a discharge flow-electron paramagnetic resonance technique. The rate constants were found to be k(HCl)(298 K) = (7.9 ± 1.3) × 10(−13) cm(3) molecule(−1) s(−1) with a weak positive temperature dependence, k(HBr) (298–460 K) = (1.04 ± 0.2) × 10(−11) cm(3) molecule(−1) s(−1), and k(HI)(298 K) = (3.0 ± 0.3) × 10(−11) cm(3) molecule(−1) s(−1), respectively. The homogeneous nature of these reactions has been experimentally tested.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::321d686a7843980155fd53b7b30a7ff0 https://pubmed.ncbi.nlm.nih.gov/36452266 Zobrazit plný text záznamu Plný text