Synthesis of a cuprite thin film by oxidation of a Cu metal precursor utilizing ultrasonically generated water vapor
Autor: | Masahiko Okamura, Ryo Yoshizawa, Kentaro Ito, Yoshio Hashimoto, Myo Than Htay |
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Jazyk: | angličtina |
Rok vydání: | 2014 |
Předmět: |
Thermal oxidation
Cuprite Materials science Inorganic chemistry Metals and Alloys Surfaces and Interfaces Substrate (electronics) Cu2O Surfaces Coatings and Films Electronic Optical and Magnetic Materials Water decomposition Chemical engineering Electrical resistivity and conductivity Impurity visual_art Phase (matter) Oxidation Materials Chemistry visual_art.visual_art_medium Thin film Water vapor Cuprous oxide Ultrasonic spray pyrolysis |
Zdroj: | THIN SOLID FILMS. 556:211-215 |
ISSN: | 0040-6090 |
Popis: | A Cu2O thin film of cuprite crystal structure was fabricated via a decomposition reaction of water vapor generated by ultrasonic vibration. The thin film, which was grown on a soda-lime glass substrate at 530 degrees C, exhibited a prominent (111) preferred orientation with an optical bandgap of about 2.1 eV and resistivity of 2.81 x 10(4) Omega cm. Generation of H-2 gas during the reaction process contributed to suppressing the growth of impurity tenorite phase. In a conventional process of thermal oxidation, the formation of the cuprite phase was always accompanied by that of the tenorite phase due to an excess oxygen exposure near the surface of the films. Article THIN SOLID FILMS. 556:211-215 (2014) |
Databáze: | OpenAIRE |
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