A short and efficient annelation sequence for the synthesis of bicyclic intermediates in the total synthesis of strigol and its analogues

Autor:	Geza Arvai, István Kádas, L. Toke
Rok vydání:	1996
Předmět:	Nef reaction Annulation Bicyclic molecule Chemistry Stereochemistry Nitro Michael reaction Total synthesis Dehydrogenation General Chemistry Conjugate
Zdroj:	Scopus-Elsevier
ISSN:	1434-4475 0026-9247
DOI:	10.1007/bf00807028
Popis:	A new annelation sequence was developed for the bicyclic diones2, intermediates in the total synthesis of strigol (1) and its analogues. The first step of the sequence is the conjugate addition of nitro alcohols4 to cyclopentenone5, followed by an alkylative cyclization step and dehydrogenation.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::312dfebe5370add3795ae47e2373f463 https://doi.org/10.1007/bf00807028 Zobrazit plný text záznamu Full text from SpringerLink