A microscale multi-functional metal-organic framework as a fluorescence chemosensor for Fe(III), Al(III) and 2-hydroxy-1-naphthaldehyde
| Autor: | Yang Kang, Lin-Pei Jin, Xiang-Jun Zheng |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
Detection limit
Scanning electron microscope Chemistry Metal ions in aqueous solution Inorganic chemistry 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Fluorescence 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Biomaterials Colloid and Surface Chemistry Dynamic light scattering Elemental analysis Metal-organic framework 0210 nano-technology Luminescence Nuclear chemistry |
| Zdroj: | Journal of Colloid and Interface Science. 471:1-6 |
| ISSN: | 0021-9797 |
| DOI: | 10.1016/j.jcis.2016.03.008 |
| Popis: | A microscale metal-organic framework [Eu(atpt)1.5(phen)(H2O)]n (H2atpt=2-aminoterephthalic acid, phen=1,10-phenanthroline) (Eu-MOF) was synthesized and characterized by elemental analysis, luminescence spectrum, powder X-ray diffraction, dynamic light scattering and scanning electron microscope. The fluorescence response of Eu-MOF to metal ions and aldehydes showed that Eu-MOF is highly selective to Fe(III), Al(III) and 2-hydroxy-1-naphthaldehyde (2-OH-NA). Eu-MOF could be utilized as a multi-functional fluorescence chemosensor for Fe(III), Al(III) and 2-hydroxy-1-naphthaldehyde (2-OH-NA). The detection limit of Fe(III), Al(III) and 2-OH-NA was 45, 10 and 36μM, respectively. The corresponding sensing mechanisms were explored. |
| Databáze: | OpenAIRE |
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