Electrochemical Synthesis of Thienoacene Derivatives: Transition‐Metal‐Free Dehydrogenative C−S Coupling Promoted by a Halogen Mediator
| Autor: | Haruka Inoue, Koichi Mitsudo, Toki Yonezawa, Hiroki Mandai, Ren Matsuo, Seiji Suga |
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| Jazyk: | angličtina |
| Rok vydání: | 2020 |
| Předmět: |
heterocycles
cyclization 010405 organic chemistry Chemistry General Medicine General Chemistry Bond formation 010402 general chemistry Electrochemistry 01 natural sciences Catalysis 0104 chemical sciences Coupling (electronics) Mediator Transition metal electrochemistry Polymer chemistry Halogen cross-coupling synthetic methods |
| Zdroj: | Angewandte Chemie International Edition. 59(20):7803-7807 |
| ISSN: | 1433-7851 |
| Popis: | The first electrochemical dehydrogenative C-S bond formation leading to thienoacene derivatives is described. Several thienoacene derivatives were synthesized by dehydrogenative C-H/S-H coupling. The addition of n Bu4 NBr, which catalytically promoted the reaction as a halogen mediator, was essential. |
| Databáze: | OpenAIRE |
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