One-pot multi-step reactions based on thiolactone chemistry: A powerful synthetic tool in polymer science
| Autor: | Pieter Espeel, Filip Du Prez |
|---|---|
| Rok vydání: | 2015 |
| Předmět: |
chemistry.chemical_classification
Polymers and Plastics Linear polymer Organic Chemistry General Physics and Astronomy Nanotechnology Polymer Physics and Astronomy(all) Ring-opening polymerization Homocysteine-thiolactone chemistry.chemical_compound Thiolactone chemistry chemistry One-pot multi-step click chemistry Materials Chemistry Click chemistry Thiolactone Organic chemistry Functionalized polymers Amine-thiol-ene conjugation |
| Zdroj: | European Polymer Journal. 62:247-272 |
| ISSN: | 0014-3057 |
| DOI: | 10.1016/j.eurpolymj.2014.07.008 |
| Popis: | One-pot multi-step reactions based on thiolactone chemistry emerged as a powerful tool to prepare tailor-made, multi-functionalized polymer architectures in a one-pot and elegant manner. This feature article highlights the most important features of this approach, demonstrated in various reactive systems including (bio-based) linear polymers, heterotelechelic polymers, polymeric networks and heterogeneous supports. This overview clearly reveals its remarkable versatility involving modular synthesis and double modification of polymers: thiolactones can be opened by a wide variety of functional amines and the released thiol can react with thiol ‘scavengers’ of choice. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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