Synthesis and Crystal Structure of One-Dimensional Copper(II) Coordination Polymer Bridged by Pyrazine Derivative
| Autor: | Hitoshi Kumagai, Yuichi Sugiyama, Susumu Kitagawa, Keiichi Adachi, Satoshi Kawata, Katsuya Inoue |
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| Rok vydání: | 2002 |
| Předmět: |
Pyrazine
Stereochemistry Coordination polymer Ligand chemistry.chemical_element General Chemistry Crystal structure Condensed Matter Physics Copper Magnetic susceptibility coordination polymer Crystallography chemistry.chemical_compound chemistry copper Diamine pyrazine derivative Molecule General Materials Science |
| Zdroj: | Molecular Crystals and Liquid Crystals. 376:71-76 |
| ISSN: | 1563-5287 1542-1406 |
| DOI: | 10.1080/10587250210797 |
| Popis: | The one-dimensional copper(II) coordination polymers [Cu(tdpd)(pda)] n ( 1 ) (H 2 tdpd=1,4,5,6-tetrahydro-5,6-dioxo-2,3-pyrazinedicarbonitrile, pda=1,2-phenylenediamine) has been synthesized and characterized. Compund 1 is a linear chain of copper(II) ions bridged by tdpd 2− dianion with terminal pda ligand. Magnetic susceptibility measurement shows antiferromagnetic couplings between the copper(II)ions. |
| Databáze: | OpenAIRE |
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