Hydroxy-assisted catalyst-free Michael addition-dehydroxylation of Baylis–Hillman adducts in poly(ethylene glycol)

Autor:	Srivari Chandrasekhar, Dolly Vijay, G. Dattatreya Sarma, Bharatam Jagadeesh, B. Saritha, V. Jagadeswar, Ch. Narsihmulu
Rok vydání:	2006
Předmět:	Poly ethylene glycol Nucleophilic addition Hydrogen bond Chemistry Organic Chemistry General Medicine Biochemistry Catalysis Adduct Solvent Intramolecular force Drug Discovery PEG ratio Polymer chemistry Michael reaction Organic chemistry
Zdroj:	Tetrahedron Letters. 47:2981-2984
ISSN:	0040-4039
DOI:	10.1016/j.tetlet.2006.02.104
Popis:	Intramolecular hydrogen bonding facilitates nucleophilic addition of sulfones to Baylis-Hillman adducts in a single step to realize the substituted allyl sulfones. The reaction is performed in PEG (400 MW) as solvent, which allows easy solvent recycling.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3011714e46bef0e019ed5551ab4b44c9 https://doi.org/10.1016/j.tetlet.2006.02.104 Zobrazit plný text záznamu Full Text from ScienceDirect