Electrochemical radical reactions of alkyl iodides: a highly efficient, clean, green alternative to tin reagents†

Autor:	Tsz-Kan Ma, Jonathan D. Wilden, Diyuan Li, Reuben J. Scott
Jazyk:	angličtina
Rok vydání:	2020
Předmět:	chemistry.chemical_classification Radical Intermolecular force chemistry.chemical_element Forming processes Tributyltin hydride General Chemistry Electrochemistry Combinatorial chemistry chemistry.chemical_compound Chemistry chemistry Reagent Tin Alkyl
Zdroj:	Chemical Science
ISSN:	2041-6539 2041-6520
Popis:	An electrochemical ‘redox-relay’ system has been developed which allows the generation of C-centered radicals. Intermolecular ‘tin-like’ radical reactions can subsequently be conducted under the most benign of conditions. The yields and efficiency of the processes are competitive and even superior in most cases to comparable conditions with tributyltin hydride. The use of air and electricity as the promotor (instead of a tin or other reagent) combined with the aqueous reaction media make this a clean and ‘green’ alternative to these classic C–C bond forming processes. A ‘green’ and high-yielding electrochemical method for performing tin-free, intermolecular radical reactions (the Giese reaction) has been developed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2fea4f31ca18f3c673b9e8370c89ab7b http://europepmc.org/articles/PMC8159374 Zobrazit plný text záznamu