Direct C–H arylation of 3-methoxythiophene catalyzed by Pd. Application to a more efficient synthesis of π-alkoxy-oligothiophene derivatives

Autor: Alfio Borghese, G. Geldhof, L. Antoine
Rok vydání: 2006
Předmět:
Zdroj: Tetrahedron Letters. 47:9249-9252
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2006.10.130
Popis: The direct regioselective C-H arylation of 3-methoxythiophene and 3,4-ethylenedioxythiophene (EDOT) was performed successfully under 'Heck-type' experimental conditions. This novel synthetic methodology has been used to prepare in a more simple way a series of oligothiophenes interesting for the electronic industry to build new synthetic organic materials. (c) 2006 Elsevier Ltd. All rights reserved.
Databáze: OpenAIRE