Insertion of an Alkene into an Ester: Intramolecular Oxyacylation Reaction of Alkenes through Acyl CO Bond Activation

Autor:	Christopher J. Douglas, Giang T. Hoang, Venkata Jaganmohan Reddy, Huy H. K. Nguyen
Rok vydání:	2011
Předmět:	chemistry.chemical_classification Alkene Decarbonylation Quinoline Homogeneous catalysis General Medicine General Chemistry Medicinal chemistry Catalysis Acylation chemistry.chemical_compound chemistry Aldol reaction Intramolecular force Organic chemistry
Zdroj:	Angewandte Chemie International Edition. 50:1882-1884
ISSN:	1433-7851
DOI:	10.1002/anie.201005767
Popis:	Notable features of the title process are the use of [Rh(cod)2]BF4/dppe catalyst system as well as the quinoline chelating group to suppress the competitive decarbonylation reaction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2f916bde1c6dbff41f3ed4091eb5c62f https://doi.org/10.1002/anie.201005767 Zobrazit plný text záznamu Plný text