trans-Bis[2-(piperazin-1-yl)ethanamine]bis(saccharinato)cobalt(II)

Autor:	Serkan Guney, Veysel T. Yilmaz, Canan Kazak
Přispěvatelé:	OMÜ
Jazyk:	angličtina
Rok vydání:	2008
Předmět:	Metal-Organic Papers Crystallography Hydrogen bond chemistry.chemical_element General Chemistry Condensed Matter Physics Bioinformatics Medicinal chemistry Carbonyl group chemistry.chemical_compound chemistry QD901-999 General Materials Science Chelation Amine gas treating Isostructural Cobalt
Zdroj:	Acta Crystallographica Section E, Vol 64, Iss 1, Pp m59-m60 (2008) Acta Crystallographica Section E: Structure Reports
Popis:	Yilmaz, Veysel/0000-0002-2849-3332; Kazak, Canan/0000-0003-2475-8775; Guney, Serkan/0000-0002-6270-5458 WOS: 000252049300055 PubMed: 21200630 In the centrosymmetric title complex, [Co(C7H4NO3S)(2)(C6H15N3)(2)], the Co-II ion is coordinated by two saccharinate (sac) anions and two neutral 2-piperazin-1-ylethanamine (ppzea) ligands, showing a distorted octahedral coordination. Sac is O-bonded via the carbonyl group, while ppzea acts as an N,N'-bidentate chelating ligand. The molecules are connected by N-H center dot center dot center dot N and N-H center dot center dot center dot O hydrogen bonds, forming a linear chain running parallel to the crystallographic a axis. The compound is isostructural with the reported Ni, Zn, and Cd analogues.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2f90e63c3575a7b8d7e987d4600aff45 https://hdl.handle.net/20.500.12712/19503 Zobrazit plný text záznamu