The bis-urea motif as a tool to functionalize self-assembled nanoribbons
| Autor: | Phh Paul Bomans, Najm Nico Sommerdijk, GE Jardl, Rjm Roeland Nolte, AL Pallas, M Monica Breurken, P.M. Frederik, Mrj Matthijn Vos, Pelg Philippe Leclere, van Olj Otto Asselen |
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| Přispěvatelé: | Biomedical Engineering, Macromolecular and Organic Chemistry |
| Jazyk: | angličtina |
| Rok vydání: | 2005 |
| Předmět: |
chemistry.chemical_classification
Chemistry Stereochemistry Hydrogen bond Ribbon diagram General Chemistry Biochemistry Combinatorial chemistry Catalysis Colloid and Surface Chemistry Molecular recognition Hydrocarbon Pulmonary surfactant Moiety Surface modification Molecule Physical Organic Chemistry |
| Zdroj: | Journal of the American Chemical Society, 127(48), 16768-16769. American Chemical Society Journal of the American Chemical Society, 127, 48, pp. 16768-16769 Journal of the American Chemical Society, 127, 16768-16769 |
| ISSN: | 0002-7863 |
| DOI: | 10.1021/ja055075n |
| Popis: | Here we present a surfactant molecule (1) containing an ammonium headgroup, in which a bis-ureido group is incorporated in its hydrocarbon chain. Due to strong hydrogen bonding interactions, 1 forms well-defined highly ordered ribbon-like aggregates in water. Moreover, we demonstrate that these ribbons can be functionalized via a modular approach through molecular recognition of other bis-urea containing molecules. The dye disperse orange and biotin were coupled to matching bis-ureido groups and incorporated into the ribbon structure. The anchoring of different functionalities in a modular approach proved to be possible using the molecular recognition capabilities of the bis-ureido moiety, thereby opening possibilities to a wide range of applications. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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