Synthesis, X-ray characterization and regium bonding interactions of a trichlorido(1-hexylcytosine)gold(III) complex
| Autor: | Juan J. Fiol, Miquel Barceló-Oliver, Antonio Frontera, Angel Terrón, Tiddo J. Mooibroek, Angel García-Raso, Jordi Buils |
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| Přispěvatelé: | Homogeneous and Supramolecular Catalysis (HIMS, FNWI) |
| Jazyk: | angličtina |
| Rok vydání: | 2020 |
| Předmět: |
Materials science
Metals and Alloys X-ray General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Nucleobase Characterization (materials science) chemistry.chemical_compound Crystallography Gold iii chemistry Stack (abstract data type) Materials Chemistry Ceramics and Composites Cytosine |
| Zdroj: | Chemical Communications, 56(24), 3524-3527. Royal Society of Chemistry |
| ISSN: | 1359-7345 |
| Popis: | Herein we report the synthesis and X-ray characterization of a gold(iii) complex of 1-hexylcytosine via N(3). The AuCl3N complexes stack on top of each other by reciprocal [Au···Cl] regium bonding interactions. After the first example 35 years ago, this is the second available structure of a cytosine nucleobase model complexed to gold(III). |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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