Introducing the concept of pulsed vapor phase copper-free surface click-chemistry using the ALD technique
| Autor: | Ivana Jelovica Badovinac, Robert Peter, Iva Šarić, Maria Kolympadi Markovic, Mato Knez, Gabriela Ambrožič, M. Ilyn, Celia Rogero |
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| Přispěvatelé: | Croatian Science Foundation, University of Rijeka, Ministry of Science, Education and Sports of the Republic of Croatia, Ministerio de Economía y Competitividad (España), European Commission, European Cooperation in Science and Technology, Saric, Iva [0000-0001-8509-3223], Peter, Robert [0000-0002-5669-1985], Kolympadi, M. [0000-0002-3442-5504], Jelovica Badovinac, Ivana [0000-0001-7911-7380], Rogero, Celia [0000-0002-2812-8853], Ilyn, M. [0000-0002-4052-7275], Knez, Mato [0000-0002-9850-1035], Ambrožić, Gabriela [0000-0002-2383-1814], Saric, Iva, Peter, Robert, Kolympadi, M., Jelovica Badovinac, Ivana, Rogero, Celia, Ilyn, M., Knez, Mato, Ambrožić, Gabriela |
| Rok vydání: | 2019 |
| Předmět: |
Propiolic acid
Materials science 010405 organic chemistry Vapor phase Metals and Alloys chemistry.chemical_element General Chemistry 010402 general chemistry 01 natural sciences Copper Catalysis 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Atomic layer deposition chemistry.chemical_compound Chemical engineering chemistry Free surface Materials Chemistry Ceramics and Composites Click chemistry Azide ALD azide-alkyne click reaction gas phase ZnO |
| Zdroj: | Digital.CSIC. Repositorio Institucional del CSIC instname |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/c9cc00367c |
| Popis: | We report for the first time on a pulsed vapor phase copper-free azide-alkyne click reaction on ZnO by using the atomic layer deposition (ALD) process technology. This reproducible and fast method is based on an in situ two-step reaction consisting of sequential exposures of ZnO to propiolic acid and benzyl azide. This work was mainly supported by the Croatian Science Foundation under project IP-2016-06-3568, and in part by the University of Rijeka under project number 16.12.2.1.01.The characterization instruments used in this work were acquired through the European Fund for Regional Development and the Ministry of Science, Education and Sports of the Republic of Croatia under the project Research Infrastructure for Campusbased Laboratories at the University of Rijeka (grant number RC.2.2.06-0001). Mato Knez and Celia Rogero are grateful for funding from the Spanish Ministry of Economy and Competitiveness (grant MAT2016-77393-R and MAT2016-78293-C6-5-R, including FEDER funds). Mato Knez acknowledges the Maria de Maeztu Units of Excellence Programme – MDM-2016-0618, and Celia Rogero acknowledges the Interreg POCTEFA V-A Spain–France–Andorra Program (EFA 194/16/TNSI) partly financed by ERDF funds. The authors acknowledge networking support within the COST action HERALD (MP1402). |
| Databáze: | OpenAIRE |
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