trans-1,2-Disiloxybenzocyclobutene, an adequate partner for the auto-oxidation: EPR/spin trapping and theoretical studies
| Autor: | Virginie Héran, Raphaël Rahmani, Béatrice Tuccio, Laurent Commeiras, Jean-Luc Parrain, Yannick Carissan, Romain Blanc, Jean Drujon |
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| Přispěvatelé: | Chimie Theorique et Modèles (CTOM), Institut des Sciences Moléculaires de Marseille (ISM2), Aix Marseille Université (AMU)-École Centrale de Marseille (ECM)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Aix Marseille Université (AMU)-École Centrale de Marseille (ECM)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), STeRéO, Institut de Chimie Radicalaire (ICR), Aix Marseille Université (AMU)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Aix Marseille Université iSm2 CTOM and ICR |
| Rok vydání: | 2014 |
| Předmět: |
Spin trapping
Autoxidation [CHIM.ORGA]Chemical Sciences/Organic chemistry 010405 organic chemistry Analytical chemistry General Physics and Astronomy 010402 general chemistry Photochemistry 01 natural sciences 3. Good health 0104 chemical sciences law.invention chemistry.chemical_compound Epr spin trapping theoretical studies Triplet oxygen chemistry law Yield (chemistry) oxygene EPR Physical and Theoretical Chemistry Electron paramagnetic resonance |
| Zdroj: | Physical Chemistry Chemical Physics Physical Chemistry Chemical Physics, Royal Society of Chemistry, 2014, 16, pp.7513-7520. ⟨10.1039/c3cp55077j⟩ Physical Chemistry Chemical Physics, 2014, 16, pp.7513-7520. ⟨10.1039/c3cp55077j⟩ |
| ISSN: | 1463-9084 1463-9076 |
| Popis: | International audience; The auto-oxidation of trans-1,2-disiloxybenzocyclobutene was found to be very efficient, giving endoperoxide in quantitative yield. Each step of the mechanism of spin-forbidden addition of triplet oxygen O2 was studied by both EPR/spin trapping and theoretical studies. |
| Databáze: | OpenAIRE |
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